While we use them when we refer to people, it is more in the sense of relationship than ownership.
Exercises - Possessive adjectives
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1) He is my mine friend.
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2) It is Mary's cat. It's her hers cat.
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3) Those are yours your cars.
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4) This is our house. It's ours our house.
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5) These are ours our animals.
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6) That is his hers shirt.
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7) This is my mother's bag. It's hers her bag.
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8) It is yours your car.
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9) This is their theirs book.
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10) My Mine coat is white.