While we use them when we refer to people, it is more in the sense of relationship than ownership.
Exercises - Possessive adjectives
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1) It is Mary's cat. It's her hers cat.
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2) He is my mine friend.
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3) This is my mother's bag. It's her hers bag.
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4) This is our house. It's our ours house.
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5) That is his hers shirt.
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6) This is theirs their book.
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7) Mine My coat is white.
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8) It is your yours car.
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9) Those are yours your cars.
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10) These are ours our animals.